there's nothing wrong with that. it doesn't matter jack which slot they're in either. if you're using 2 different speeds of memory, 266/333, the motherboard will run both sticks at the lower speed, 266, instead of overclocking the other to match. also, if you have a chipset that supports dual channel, you need ram with the same speed and quantity. identical sticks is recommended.
a lot of the time people will buy higher speed memory to give more headroom for overclocking. but running slower memory can slow the whole system down. you want it to at least match the motherboard's rated memory speed.
i would highly recommend you getting either a single 1gb stick or 2 matching 512mb sticks if your system supports dual channel. not that what you have is bad, but you're not getting the performance you could.
people tend to look at memory like they do cpu's. it's not only quantity that matters, the speed plays a big role too. also latency is a large factor. a lot of people tend to judge cpu's by gigahertz, and that's the wrong way to do it. there are many more factors that are more important.
question, what video card did you put in it? i'm guessing from the memory speeds that it's an agp system.
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